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Journal of Science and Engineering Papers

Doi: https://doi.org/10.62275/josep.24.1000001

ISSN: 3006-3191 (Online)

ISSN: 3079-8175 (Print)

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Preparation of Ni(II)Fe(III)-layered double oxide and its application for the removal of methyl orange dye: Adsorption isotherm and thermodynamic study

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Original Research Article
Nanomaterials
Preparation of Ni(II)Fe(III)-layered double oxide and its application for the removal of methyl orange dye: Adsorption isotherm and thermodynamic study
Aneek Krishna Karmakar, Md. Saif Hasan and Humaira Hasin
Dept. of Applied Chemistry and Chemical Engineering, University of Rajshahi
Year: 2024
Page: 26-30
Doi: 10.62275/josep.24.1000005

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Abstract

The Ni(II)Fe(III)-LDO has been synthesized by calcination of Ni(II)Fe(III)-LDH at 500 ℃. The prepared LDO is applied in the treatment of Methyl Orange (MO) dye from a synthetic solution. A batch of experiments is conducted to examine the effects of varying adsorption parameters, i.e. initial dye concentrations and temperature. The results indicate that the adsorption of MO increases with rising dye concentration and solution temperature. Temkin, Freundlich, and Langmuir isotherms are analyzed to investigate the adsorption process at different pH levels. Various thermodynamic parameters such as ΔS, ΔH and ΔGº have also been calculated. The adsorption of MO dyes on the Ni(II)Fe(III)-LDO is found endothermic and non-spontaneous in nature. The findings reveal the adsorption process is physical sorption.

References

  1. Saravanan, R., Gupta, V. K., Narayanan, V., and Stephen, A., (2014). Visible light degradation of textile effluent using novel catalyst ZnO/γ-Mn2O3. Journal of the Taiwan Institute of Chemical Engineers, 45(4): 1910-1917.
  2. Allen, S. J., Gan, Q., Matthews, R., and Johnson, P. A., (2005). Kinetic modeling of the adsorption of basic dyes by kudzu. Journal of Colloid and Interface Science, 286(1): 101-109.
  3. Tunali, S., Özcan, A. S., Özcan, A., and Gedikbey, T., (2006). Kinetics and equilibrium studies for the adsorption of Acid Red 57 from aqueous solutions onto calcined-alunite. Journal of Hazardous Materials, 135(1): 141-148.
  4. Küçükosmanoğlu, M., Gezici, O., and Ayar, A., (2006). The adsorption behaviors of Methylene Blue and Methyl Orange in a diaminoethane sporopollenin-mediated column system. Separation and Purification Technology, 52(2): 280-287.
  5. Mittal, A., Malviya, A., Kaur, D., Mittal, J., and Kurup, L., (2007). Studies on the adsorption kinetics and isotherms for the removal and recovery of Methyl Orange from wastewaters using waste materials. Journal of Hazardous Materials, 148(1): 229-240.
  6. Ravikumar, K., Deebika, B., and Balu, K., (2005). Decolourization of aqueous dye solutions by a novel adsorbent: Application of statistical designs and surface plots for the optimization and regression analysis. Journal of Hazardous Materials, 122(1): 75-83.
  7. Gupta, V. K., Kumar, R., Nayak, A., Saleh, T. A., and Barakat, M. A., (2013). Adsorptive removal of dyes from aqueous solution onto carbon nanotubes: A review. Advances in Colloid and Interface Science, 193-194: 24-34.
  8. Hameed, B. H. and Ahmad, A. A., (2009). Batch adsorption of methylene blue from aqueous solution by garlic peel, an agricultural waste biomass. Journal of Hazardous Materials, 164(2): 870-875.
  9. Mittal, A., Mittal, J., Malviya, A., and Gupta, V. K., (2009). Adsorptive removal of hazardous anionic dye “Congo red” from wastewater using waste materials and recovery by desorption. Journal of Colloid and Interface Science, 340(1): 16-26.
  10. Mittal, A., Mittal, J., Malviya, A., Kaur, D., and Gupta, V. K., (2010). Decoloration treatment of a hazardous triarylmethane dye, Light Green SF (Yellowish) by waste material adsorbents. Journal of Colloid and Interface Science, 342(2): 518-527.
  11. Saleh, T. A. and Gupta, V. K., (2012). Photo-catalyzed degradation of hazardous dye methyl orange by use of a composite catalyst consisting of multi-walled carbon nanotubes and titanium dioxide. Journal of Colloid and Interface Science, 371(1): 101-106.
  12. Idan, I. J., Abdullah, L. C., Choong, T. S. Y., and Jamil, S. N. A. B. M., (2017). Equilibrium, kinetics and thermodynamic adsorption studies of acid dyes on adsorbent developed from kenaf core fiber. Adsorption Science & Technology, 36(1-2): 694-712.
  13. Gupta, V. K., Ali, I., Saleh, T. A., Nayak, A., and Agarwal, S., (2012). Chemical treatment technologies for waste-water recycling—an overview. RSC Advances, 2(16): 6380-6388.
  14. Zhang, L., Hui, K. N., Hui, K. S., Chen, X., Chen, R., and Lee, H., (2016). Role of graphene on hierarchical flower-like NiAl layered double hydroxide-nickel foam-graphene as binder-free electrode for high-rate hybrid supercapacitor. International Journal of Hydrogen Energy, 41(22): 9443-9453.
  15. Lv, Z., Yang, S., Zhu, H., Chen, L., Alharbi, N. S., Wakeel, M., Wahid, A., and Chen, C., (2018). Highly efficient removal of As(V) by using NiAl layered double oxide composites. Applied Surface Science, 448: 599-608.
  16. Zhang, J., Zhou, Q., and Ou, L., (2012). Kinetic, isotherm, and thermodynamic studies of the adsorption of methyl orange from aqueous solution by chitosan/alumina composite. Journal of Chemical & Engineering Data, 57(2): 412-419.
  17. Shakir, K., Elkafrawy, A. F., Ghoneimy, H. F., Elrab Beheir, S. G., and Refaat, M., (2010). Removal of rhodamine B (a basic dye) and thoron (an acidic dye) from dilute aqueous solutions and wastewater simulants by ion flotation. Water Research, 44(5): 1449-1461.
  18. Safa, Y. and Bhatti, H. N., (2011). Biosorption of Direct Red-31 and Direct Orange-26 dyes by rice husk: Application of factorial design analysis. Chemical Engineering Research and Design, 89(12): 2566-2574.
  19. Langmuir, I., (1918). The adsorption of gases on plane surfaces of glass, mica and platinum. Journal of the American Chemical society, 40(9): 1361-1403.
  20. Freundlich, H., (1906). Over the adsorption in solution. Z Phys Chemie-Int J res. Phys Chem Chem Phys, 57: 1361-1368.
  21. Temkin, M., (1940). Kinetics of ammonia synthesis on promoted iron catalysts. Acta physiochim. URSS, 12: 327-356.
  22. Amin, M., Alazba, A., and Shafiq, M., (2019). Comparative study for adsorption of methylene blue dye on biochar derived from orange peel and banana biomass in aqueous solutions. Environmental Monitoring and Assessment, 191: 1-14.
  23. Watkins, R., Weiss, D., Dubbin, W., Peel, K., Coles, B., and Arnold, T., (2006). Investigations into the kinetics and thermodynamics of Sb (III) adsorption on goethite (α-FeOOH). Journal of colloid and interface science, 303(2): 639-646.
  24. Kim, T.-K., Son, Y.-A., and Lim, Y.-J., (2007). Thermodynamic analysis of 1, 4-diaminoanthraquinone adsorption on polyethylene terephthalate in alkane media. Dyes and pigments, 72(2): 246-250.
  25. Muhire, C., Zhang, D., and Xu, X., (2022). Adsorption of uranium (VI) ions by LDH intercalated with l-methionine in acidic water: Kinetics, thermodynamics and mechanisms. Results in Engineering, 16: 100686.

How to Cite

Aneek Krishna Karmakar, Md. Saif Hasan and Humaira Hasin
I.H. 2024. Preparation of Ni(II)Fe(III)-layered double oxide and its application for the removal of methyl orange dye: Adsorption isotherm and thermodynamic study. Journal of Science and Engineering Papers . 
January 15, 2024.
  Doi: 10.62275/josep.24.1000005.
Aneek Krishna Karmakar, Md. Saif Hasan and Humaira Hasin
Preparation of Ni(II)Fe(III)-layered double oxide and its application for the removal of methyl orange dye: Adsorption isotherm and thermodynamic study.
  journal 2024, 15.
Aneek Krishna Karmakar, Md. Saif Hasan and Humaira Hasin
I.H. 2024. Preparation of Ni(II)Fe(III)-layered double oxide and its application for the removal of methyl orange dye: Adsorption isotherm and thermodynamic study. .Journal of Science and Engineering Papers . 
15 (1).
  https://doi.org/10.62275/josep.24.1000005.
Aneek Krishna Karmakar, Md. Saif Hasan and Humaira Hasin
I.H. Preparation of Ni(II)Fe(III)-layered double oxide and its application for the removal of methyl orange dye: Adsorption isotherm and thermodynamic study. Journal of Science and Engineering Papers . 
2024.
Aneek Krishna Karmakar, Md. Saif Hasan and Humaira Hasin
2024." Preparation of Ni(II)Fe(III)-layered double oxide and its application for the removal of methyl orange dye: Adsorption isotherm and thermodynamic study." Journal of Science and Engineering Papers . 
15 (1).
  https://doi.org/10.62275/josep.24.1000005.
Aneek Krishna Karmakar, Md. Saif Hasan and Humaira Hasin
I.H. 2024. " Preparation of Ni(II)Fe(III)-layered double oxide and its application for the removal of methyl orange dye: Adsorption isotherm and thermodynamic study." Journal of Science and Engineering Papers . 
15 (1).
  https://doi.org/10.62275/josep.24.1000005.
Aneek Krishna Karmakar, Md. Saif Hasan and Humaira Hasin
, "Preparation of Ni(II)Fe(III)-layered double oxide and its application for the removal of methyl orange dye: Adsorption isotherm and thermodynamic study". .Journal of Science and Engineering Papers . 
  journal Jan, 2024.
Aneek Krishna Karmakar, Md. Saif Hasan and Humaira Hasin
"Preparation of Ni(II)Fe(III)-layered double oxide and its application for the removal of methyl orange dye: Adsorption isotherm and thermodynamic study." Journal of Science and Engineering Papers . 
Jan, 2024.
  https://doi.org/10.62275/josep.24.1000005.
Aneek Krishna Karmakar, Md. Saif Hasan and Humaira Hasin
"Preparation of Ni(II)Fe(III)-layered double oxide and its application for the removal of methyl orange dye: Adsorption isotherm and thermodynamic study." Journal of Science and Engineering Papers . 
(Jan 15, 2024).
  https://doi.org/10.62275/josep.24.1000005.
Aneek Krishna Karmakar, Md. Saif Hasan and Humaira Hasin
Preparation of Ni(II)Fe(III)-layered double oxide and its application for the removal of methyl orange dye: Adsorption isotherm and thermodynamic study. Journal of Science and Engineering Papers . 
  journal [ Internet ] 15 Jan, 2024.
  [ Cited 15 Jan, 2024 ]
15 (1).
  https://doi.org/10.62275/josep.24.1000005.

Keywords

methyl Orange, layered double oxide, isotherms, adsorption, thermodynamics

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